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The Second Law of Thermodynamics: If you think things are in a mess now, just wait!
Sep 30, 2025
We define thermodynamics ... as the investigation of the dynamical and thermal properties of bodies, deduced entirely from the first and second law of thermodynamics, without speculation as to the molecular constitution.
It is often said that the progression from simple to complex runs counter to the normal statistics of chance that are formalized in the Second Law of Thermodynamics. Strictly speaking, we could avoid this criticism simply by insisting that the Second Law does not apply to living systems in the environment in which we find them. For the Second Law applies only when there is no overall flow of energy into or out of a system, whereas all living systems are sustained by a net inflow of energy.
Nothing in life is certain except death, taxes, and the second law of thermodynamics.
Fourth Law of Thermodynamics: If the probability of success is not almost one, then it is damn near zero.
Thermodynamics, correctly interpreted, does not just allow Darwinian evolution; it favors it.
Nothing in life is certain except death, taxes and the second law of thermodynamics. All three are processes in which useful or accessible forms of some quantity, such as energy or money, are transformed into useless, inaccessible forms of the same quantity. That is not to say that these three processes don't have fringe benefits: taxes pay for roads and schools; the second law of thermodynamics drives cars, computers and metabolism; and death, at the very least, opens up tenured faculty positions.
Tell me it's never been done. Because the only real laws in this world-the only things we really know-are the two postulates of relativity, the three laws of Newton, the four laws of thermodynamics, and Maxwell's equation-no, scratch that, the only things we really know are Maxwell's equations, the three laws of Newton, the two postulates of relativity, and the periodic table. That's all we know that's true. All the rest are man's laws
It was not easy for a person brought up in the ways of classical thermodynamics to come around to the idea that gain of entropy eventually is nothing more nor less than loss of information.
The production of motion in the steam engine always occurs in circumstances which it is necessary to recognize, namely when the equilibrium of caloric is restored, or (to express this differently) when caloric passes from the body at one temperature to another body at a lower temperature.
It is a remarkable fact that the second law of thermodynamics has played in the history of science a fundamental role far beyond its original scope. Suffice it to mention Boltzmann's work on kinetic theory, Planck's discovery of quantum theory or Einstein's theory of spontaneous emission, which were all based on the second law of thermodynamics.
A good many times I have been present at gatherings of people who, by the standards of the traditional culture, are thought highly educated and who have with considerable gusto been expressing their incredulity at the illiteracy of scientists. Once or twice I have been provoked and have asked the company how many of them could describe the Second Law of Thermodynamics. The response was cold: it was also negative. Yet I was asking something which is about the scientific equivalent of: Have you read a work of Shakespeare's?
Cost is always an object - the second law of thermodynamics sees to that
Just like a computer, we must remember things in the order in which entropy increases. This makes the second law of thermodynamics almost trivial. Disorder increases with time because we measure time in the direction in which disorder increases. You can't have a safer bet than that!
There were a number of particularly delightful incidents. There is, for example, the physicist who introduced me to one of my favorite laws, which he described as Murphys law or the fourth law of thermodynamics (actually there were only three last I heard) which states: If anything can go wrong it will.
It is possible to express the laws of thermodynamics in the form of independent principles , deduced by induction from the facts of observation and experiment, without reference to any hypothesis as to the occult molecular operations with which the sensible phenomena may be conceived to be connected; and that course will be followed in the body of the present treatise. But, in giving a brief historical sketch of the progress of thermodynamics, the progress of the hypothesis of thermic molecular motions cannot be wholly separated from that of the purely inductive theory.
A theory is the more impressive the greater the simplicity of its premises is, the more different kinds of things it relates, and the more extended is its area of applicability. Therefore the deep impression which classical thermodynamics made upon me. It is the only physical theory of universal content concerning which I am convinced that within the framework of the applicability of its basic concepts, it will never be overthrown.
Software is like entropy. It is difficult to grasp, weighs nothing, and obeys the second law of thermodynamics; i.e. it always increases.
If someone points out to you that your pet theory of the universe is in disagreement with Maxwell's equations - then so much the worse for Maxwell's equations. If it is found to be contradicted by observation - well, these experimentalists do bungle things sometimes. But if your theory is found to be against the second law of thermodynamics I can give you no hope; there is nothing for it but to collapse in deepest humiliation.
If your theory is found to be against the second law of thermodynamics I give you no hope; there is nothing for it but to collapse in deepest humiliation.
The elevator shaft was a kind of heat sink. Hot food was cold by the time it arrived. Cold food got colder. No one knew what would happen to ice cream, but it would probably involve some rewriting of the laws of thermodynamics.
Physics admits of a lovely unification, not just at the level of fundamental forces, but when considering its extent and implications. Classifications like "optics" or "thermodynamics" are just straitjackets, preventing physicists from seeing countless intersections.
I don't. We've had three technological revolutions that have changed the course of human history, all driven by physics. In the first, the industrial revolution, physicists developed Newtonian mechanics and thermodynamics, which gave us the steam engine and machine power. The second technological revolution was the electricity revolution. That gave us radio, television, and telecommunications. Then, physicists developed the laser and the transistor.
In the eighteenth century it was often convenient to regard man as a clockwork automaton. In the nineteenth century, with Newtonian physics pretty well assimilated and a lot of work in thermodynamics going on, man was looked on as a heat engine, about 40 per cent efficient. Now in the twentieth century, with nuclear and subatomic physics a going thing, man had become something which absorbs X-rays, gamma rays and neutrons.
Willard Gibbs did for statistical mechanics and for thermodynamics what Laplace did for celestial mechanics and Maxwell did for electrodynamics, namely, made his field a well-nigh finished theoretical structure.
And when my body shall cease, my soul will still be yours, Claire? I swear by my hope of heaven, I will not be parted from you." The wind stirred the leaves of the chestnut trees nearby, and the scents of late summer rose up rich around us; pine and grass and strawberries, sun-warmed stone and cool water, and the sharp, musky smell of his body next to mine. "Nothing is lost, Sassenach; only changed." "That's the first law of thermodynamics," I said, wiping my nose. "No," he said. "That's faith.
Ludwig Boltzmann, who spent much of his life studying statistical mechanics, died in 1906 by his own hand. Paul Ehrenfest, carrying on the work, died similarly in 1933. Now it is our turn to study statistical mechanics.
Pyramids, cathedrals, and rockets exist not because of geometry, theories of structures, or thermodynamics, but because they were first a picture- literally a vision-in the minds of those who built them. Society is where it is today because people had the perception; the images and the imagination; the creativity that the Arts provide, to make the world the place we live in today.
Bureaucracies temporarily suspend the Second Law of Thermodynamics. In a bureaucracy, it's easier to make a process more complex than to make it simpler, and easier to create a new burden than kill an old one.
Once I got home, I sulked for a while. All my brilliant plans foiled by thermodynamics. Damn you, Entropy!
The laws of thermodynamics may be regarded as particular cases of more general laws, applicable to all such states of matter as constitute Energy , or the capacity to perform work, which more general laws form the basis of the science of energetics, a science comprehending, as special branches, the theories of motion, heat, light , electricity , and all other physical phenomena.
Evolution in the biosphere is therefore a necessarily irreversible process defining a direction in time; a direction which is the same as that enjoined by the law of increasing entropy, that is to say, the second law of thermodynamics. This is far more than a mere comparison: the second law is founded upon considerations identical to those which establish the irreversibility of evolution. Indeed, it is legitimate to view the irreversibility of evolution as an expression of the second law in the biosphere.
To pretend that civilization can exist without destroying its own landbase and the landbases and cultures of others is to be entirely ignorant of history, biology, thermodynamics, morality, and self-preservation.
The use of thermodynamics in biology has a long history rich in confusion.
Professor Eddington has recently remarked that 'The law that entropy always increases - the second law of thermodynamics - holds, I think, the supreme position among the laws of nature'. It is not a little instructive that so similar a law [the fundamental theorem of natural selection] should hold the supreme position among the biological sciences.
Everybody can be great, because everybody can serve. [...] You only need a heart full of grace.
Everybody can be great...because anybody can serve. You don't have to have a college degree to serve.
You only need a heart full of grace
I find the big bang, really quite fascinating. I mean, here you have all these highfalutin scientists and they're saying it was this gigantic explosion and everything came into perfect order. Now these are the same scientists that go around touting the second law of thermodynamics, which is entropy, which says that things move toward a state of disorganization.
According to Bastardi, human-induced climate change "contradicts what we call the 1st law of thermodynamics. Energy can be neither created nor destroyed. So to look for input of energy into the atmosphere, you have to come from a foreign source.
In fact, the science of thermodynamics began with an analysis, by the great engineer Sadi Carnot, of the problem of how to build the best and most efficient engine, and this constitutes one of the few famous cases in which engineering has contributed to fundamental physical theory. Another example that comes to mind is the more recent analysis of information theory by Claude Shannon. These two analyses, incidentally, turn out to be closely related.
The laws of thermodynamics restrict all technologies, man's as well as nature's, and apply to all economic systems whether capitalist, communist, socialist, or fascist. We do not create or destroy (produce or consume) anything in a physical sense- we merely transform or rearrange. And the inevitable cost of arranging greater order in one part of the system (the human economy) is creating a more than offsetting amount of disorder elsewhere (the natural environment).
It reflects a prevailing myth that production technology is no more amenable to human judgment or social interests than the laws of thermodynamics, atomic structure or biological inheritance.
There is only one law of Nature-the second law of thermodynamics-which recognises a distinction between past and future more profound than the difference of plus and minus. It stands aloof from all the rest. ... It opens up a new province of knowledge, namely, the study of organisation; and it is in connection with organisation that a direction of time-flow and a distinction between doing and undoing appears for the first time.
Enchanting is not the word that would immediately spring to mind when describing a play that deals with fractal geometry, iterated algorithms, chaos theory and the second law of thermodynamics, but it is a perfect fit for Tom Stoppard's astonishing 1993 play, which is as beautiful as it is brilliant. This is one Stoppard drama that you don't have to be Einstein to understand -- you can feel it as well as think it. (...) Breathtaking, exhilarating and deeply satisfying.
In thermodynamics as well as in other branches of molecular physics , the laws of phenomena have to a certain extent been anticipated, and their investigation facilitated, by the aid of hypotheses as to occult molecular structures and motions with which such phenomena are assumed to be connected. The hypothesis which has answered that purpose in the case of thermodynamics, is called that of "molecular vortices," or otherwise, the "centrifugal theory of elasticity.
If Thought is capable of being classed with Electricity, or Will with chemical affinity, as a mode of motion, it seems necessary to fall at once under the second law of thermodynamics as one of the energies which most easily degrades itself, and, if not carefully guarded, returns bodily to the cheaper form called Heat. Of all possible theories, this is likely to prove the most fatal to Professors of History.
Everybody can be great...because anybody can serve. You don't have to have a college degree to serve. You don't have to make your subject and verb agree to serve. You only need a heart full of grace. A soul generated by love.
Every heat engineer knows he can design his heat engine reliably and accurately on the foundation of the second law [of thermodynamics]. Run alongside one of the molecules, however, and ask it what it thinks of the second law. It will laugh at us. It never heard of the second law. It does what it wants. All the same, a collection of billions upon billions of such molecules obeys the second law with all the accuracy one could want
Of all the statements that have been made with respect to theories on the origin of life, the statement that the Second Law of Thermodynamics poses no problem for an evolutionary origin of life is the most absurd… The operation of natural processes on which the Second Law of Thermodynamics is based is alone sufficient, therefore, to preclude the spontaneous evolutionary origin of the immense biological order required for the origin of life.